{"id":2750,"date":"2011-10-16T10:02:48","date_gmt":"2011-10-16T02:02:48","guid":{"rendered":"http:\/\/www.g4e.cn\/wordpress\/?p=2750"},"modified":"2013-11-18T15:57:43","modified_gmt":"2013-11-18T07:57:43","slug":"on-reactive-hot-melt-pur-hm","status":"publish","type":"post","link":"http:\/\/www.g4e.cn\/wordpress\/adhesiveknowledge\/2750.html","title":{"rendered":"\u5173\u4e8e\u53cd\u5e94\u6027\u70ed\u7194\u80f6\u2014PUR-HM"},"content":{"rendered":"

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1\u3001\u70ed\u7194\u80f6\u7684\u5f00\u53d1\u52a8\u5411<\/p>\n

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2\u3001\u4e0d\u540c\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6\u7c98\u5408\u5242[3]<\/p>\n

2.1\u4ee5EVA\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6<\/p>\n

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MFR\u503c\u4e3a\u5176\u7194\u878d\u65f6\u7684\u6d41\u52a8\u6027\u6307\u6807\uff0c\u5b83\u4e0eEVA\u7684\u5206\u5b50\u91cf\u76f4\u63a5\u6709\u5173,\u540c\u65f6\u4e0eEVA\u7684\u7194\u878d\u7c98\u5ea6\u6210\u76f4\u7ebf\u5173\u7cfb\u3002<\/p>\n

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2.2\u4ee5\u5408\u6210\u6a61\u80f6\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6<\/p>\n

\u5e38\u7528\u7684\u5408\u6210\u6a61\u80f6\u4e3b\u6210\u5206\u6709\u4ee5\u4e0b4\u79cd\uff0c\u5373SBS\uff08\u82ef\u4e59\u70ef\uff0d\u4e01\u4e8c\u70ef\uff0d\u82ef\u4e59\u70ef\uff09\u3001SIS\uff08\u82ef\u4e59\u70ef\uff0d\u5f02\u620a\u4e8c\u70ef\uff0d\u82ef\u4e59\u70ef\uff09\u3001SEBS\uff08\u82ef\u4e59\u70ef\uff0d\u4e59\u70ef\u2022\u4e01\u70ef\uff0d\u82ef\u4e59\u70ef\uff09\u3001SEPS\uff08\u82ef\u4e59\u70ef\uff0d\u4e59\u70ef\uff0d\u4e19\u70ef\uff0d\u82ef\u4e59\u70ef\uff09\u3002\u5b83\u4eec\u5206\u5b50\u6392\u5217\u6bd4\u8f83\u6574\u9f50\uff0c\u4e24\u7aef\u4ee5\u82ef\u4e59\u70ef\u5c01\u7aef\uff0c\u5982SBS\u3001SIS\u3001SEBS\u3002<\/p>\n

\u4ee5\u8fd9\u4e9b\u5408\u6210\u6a61\u80f6\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6\uff0c\u4f18\u70b9\u662f\u4e0d\u9700\u8981\u786b\u5316\uff0c\u8010\u8815\u53d8\u6027\u8f83\u597d\uff0c\u4e0e\u5404\u79cd\u6dfb\u52a0\u5242\u76f8\u5bb9\u6027\u597d\uff0c\u80fd\u5bf9\u5404\u79cd\u6750\u6599\u8fdb\u884c\u7c98\u63a5\uff1b\u7f3a\u70b9\u662f\u8010\u70ed\u6027\u8f83\u5dee\uff08\u5728\u4f4e\u8d1f\u8377\u4e0b\u4f7f\u7528\u6e29\u5ea6\u4e3a77\uff5e80\u2103\uff09\uff0c\u4e0d\u8010\u7d2b\u5916\u7ebf\u7167\u5c04\uff0c\u4e0d\u8010\u7f9f\u7c7b\u6709\u673a\u6eb6\u5242\u3002<\/p>\n

\u8fd1\u5e74\u6765\u8fd9\u7c7b\u70ed\u7194\u80f6\u5e94\u7528\u8303\u56f4\u4e0d\u65ad\u6269\u5927\uff0c\u5f00\u53d1\u51fa\u4e0d\u5c11\u9ad8\u9644\u52a0\u503c\u7528\u9014\u7684\u65b0\u54c1\u79cd\u3002\u5982\u7528\u4e8e\u6c7d\u8f66\u5c3e\u706f\u5bc6\u5c01\u7684\u4e13\u7528\u5bc6\u5c01\u80f6\uff0c\u4e0d\u4ec5\u89e3\u51b3\u4e86\u5c3e\u706f\u7684\u5bc6\u5c01\u6027\uff0c\u4e5f\u4fbf\u4e8e\u66f4\u6362\u706f\u6ce1\uff0c\u4e14\u5728\u6c7d\u8f66\u62a5\u5e9f\u65f6\u4e5f\u4fbf\u4e8e\u5c06\u6b64\u5bc6\u5c01\u80f6\u56de\u6536\u518d\u5229\u7528\u3002\u4e3a\u4e86\u63d0\u9ad8\u7c98\u5408\u5242\u7684\u8f6f\u5316\u70b9\uff0c\u5728\u914d\u65b9\u4e2d\u52a0\u5165\u805a\u82ef\u919a\uff0c\u540c\u65f6\u4e5f\u63d0\u9ad8\u4e86\u5b83\u7684\u8010\u70ed\u6027\u548c\u7c98\u63a5\u6027\u3002\u5728\u914d\u65b9\u4e2d\u52a0\u5165\u52a0\u6c22\u7684\u73af\u72b6\u6811\u8102\u3001\u805a\u4e01\u70ef\u6df7\u5408\u7269\u53ef\u4ee5\u63d0\u9ad8\u5176\u8f6f\u5316\u70b9\u5e76\u964d\u4f4e\u7194\u878d\u7c98\u5ea6,\u5373\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u63d0\u9ad8\u4e86\u8010\u70ed\u6027\u3002\u4e3a\u4e86\u63d0\u9ad8\u8fd9\u7c7b\u7c98\u5408\u5242\u7684\u521d\u671f\u7c98\u63a5\u529b\uff0c\u4e0d\u964d\u4f4e\u5176\u8010\u5bd2\u6027\u53ca\u8010\u70ed\u6027\u7684\u4f18\u70b9\uff0c\u4e5f\u53ef\u63ba\u5165\u6dfb\u52a0\u5242\uff0c\u5982\u5728SEBS\u4e2d\u52a0\u5165\u91d1\u5c5e\u76d0\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u4f7f\u5176\u6210\u4e3a\u79bb\u5b50\u4ea4\u8054\u7684\u805a\u5408\u7269\u3002\u5728\u914d\u65b9\u4e2d\u518d\u52a0\u5165\u589e\u7c98\u6027\u6811\u8102\u3001\u589e\u5851\u5242\u7b49\u6dfb\u52a0\u5242\uff0c\u5f62\u6210\u4e13\u7528\u7684\u914d\u65b9\u3002\u82e5\u7528\u4e8e\u5bf9\u805a\u78b3\u9178\u916f\u7684\u7c98\u63a5\u4e2d\uff0c\u5219\u5728\u6b64\u70ed\u7194\u80f6\u4e2d\u52a0\u5165\u5206\u5b50\u7b5b\u4ee5\u5438\u6536\u6389\u805a\u78b3\u9178\u916f\u5728\u53d7\u70ed\u65f6\u5f15\u8d77\u6c34\u89e3\u800c\u5728\u7c98\u63a5\u754c\u9762\u5904\u4ea7\u751f\u7684\u6c34\u84b8\u6c14\u6c14\u6ce1\u3002\u53c8\u5982\u91c7\u7528\u5149\u56fa\u5316\u53cd\u5e94\u6765\u63d0\u9ad8\u8010\u70ed\u6027\u7b49\u7b49\u65b0\u6280\u672f\u3001\u65b0\u65b9\u6cd5\u3002<\/p>\n

2.3\u4ee5\u70ed\u5851\u6027\u805a\u916f\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6<\/p>\n

\u70ed\u5851\u6027\u805a\u916f\u662f\u7531\u4e8c\u7fa7\u9178\u4e0e\u4e8c\u5143\u9187\u7f29\u805a\u800c\u6210\u7684\u3002\u5e38\u7528\u7684\u4e8c\u7fa7\u9178\u6709\u5bf9\u82ef\u4e8c\u7532\u9178\u3001\u95f4\u82ef\u4e8c\u7532\u9178\u3001\u90bb\u82ef\u4e8c\u7532\u9178\u9150\u3001\u4e01\u4e8c\u9178\u3001\u58ec\u4e8c\u9178\u3001\u7678\u4e8c\u9178\u7b49\u3002\u5e38\u7528\u7684\u4e8c\u5143\u9187\u6709\u4e59\u4e8c\u9187\u3001\u4e19\u4e8c\u9187\u30011,4\u4e01\u4e8c\u9187\u30011,5\u620a\u4e8c\u9187\u30011,6\u5df1\u4e8c\u9187\u7b49\u3002\u6309\u7528\u6237\u9700\u8981\u9009\u7528\u5404\u79cd\u4e8c\u7fa7\u9178\u4e0e\u4e8c\u5143\u9187\u901a\u8fc7\u7f29\u805a\u5236\u6210\u70ed\u5851\u6027\u805a\u916f\u3002\u4ee5\u5176\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6,\u9664\u4e86\u52a0\u5165\u4e0a\u8ff0\u5fc5\u8981\u7684\u6dfb\u52a0\u5242\u5916\uff0c\u8fd8\u53ef\u6839\u636e\u7528\u9014\u518d\u6dfb\u52a0\u963b\u71c3\u5242\u3001\u589e\u5f3a\u6750\u6599\uff08\u5982\u73bb\u7483\u7ea4\u7ef4\u6216\u78b3\u7ea4\u7ef4\uff09\u7b49\u7b49\u6765\u6ee1\u8db3\u7528\u6237\u8981\u6c42\u3002\u6b64\u7c7b\u70ed\u7194\u80f6\u7684\u7279\u5f81\u662f\uff1a\u88ab\u7c98\u63a5\u6750\u6599\u8303\u56f4\u5e7f\u53ca\u7c98\u63a5\u6027\u8f83\u597d\u3001\u70ed\u7a33\u5b9a\u6027\u4e5f\u8f83\u597d\uff08\u8010\u70ed\u3001\u8010\u5bd2\u53ca\u8010\u51b7\u70ed\u4ea4\u53d8\u65f6\u4fdd\u6301\u7c98\u63a5\u6027\u4e0d\u53d8\uff09\uff0c\u8010\u836f\u54c1\u6027\u53ca\u7535\u6c14\u7279\u6027\u5747\u4f18,\u5e76\u4e14\u4e0d\u4ea7\u751f\u516c\u5bb3\u7b49\u3002<\/p>\n

2.4\u4ee5\u805a\u9170\u80fa\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6\u3002<\/p>\n

\u805a\u9170\u80fa\u4e00\u822c\u7531\u4e8c\u5143\u9178\u4e0e\u4e8c\u5143\u80fa\u7f29\u805a\u800c\u6210\uff0c\u901a\u5e38\u4ee5\u5c3c\u9f99\u4e3a\u4ee3\u8868\u3002\u5728\u70ed\u7194\u80f6\u4e2d\u4f5c\u4e3a\u4e3b\u6210\u5206\u7684\u805a\u9170\u80fa\u5b9e\u9645\u4f7f\u7528\u7684\u4e8c\u5143\u9178\u4e3a\u5df1\u4e8c\u9178\u3001\u58ec\u4e8c\u9178\u3001\u7678\u4e8c\u9178\u7b49\uff0c\u5b83\u4eec\u8fd8\u8d77\u8c03\u8282\u70ed\u7194\u80f6\u7684\u8f6f\u5316\u70b9\u4e0e\u7ed3\u6676\u6027\u7684\u4f5c\u7528\uff1b\u4e8c\u5143\u80fa\u4e3a\u4e59\u4e8c\u80fa\u3001\u5df1\u4e8c\u80fa\u3001\u82ef\u4e8c\u7532\u6491\u4e8c\u80fa\u30014,4\u2019\u4e8c\u6c28\u57fa\uff0d\u4e8c\u73af\u5df1\u80fa\u3001p,p\u2032\u7532\u6491\u4e8c\u5143\u80fa\u3001\u70f7\u9187\u80fa\u7b49\u3002<\/p>\n

\u6b64\u7c7b\u70ed\u7194\u80f6\u6309\u5e94\u7528\u8981\u6c42\u9009\u62e9\u6027\u5730\u52a0\u5165\u589e\u7c98\u5242\u3001\u6297\u6c27\u5316\u5242\u3001\u589e\u5851\u5242\uff0c\u586b\u6599\u7b49\u6dfb\u52a0\u5242\u3002\u5b83\u4eec\u4e0e\u677e\u9999\u6216\u677e\u9999\u884d\u751f\u7269\u3001\u9999\u8c46\u916e\u3001\u831a\u6811\u8102\u3001\u82ef\u915a\u6811\u8102\u3001\u841c\u70ef\u6811\u8102\u7b49\u7684\u76f8\u5bb9\u6027\u8f83\u597d\uff0c\u5bf9\u5404\u79cd\u589e\u5851\u5242\u7684\u76f8\u5bb9\u6027\u4e5f\u8f83\u597d\u3002<\/p>\n

2.5\u4ee5\u805a\u70ef\u70c3\u4e3a\u4e3b\u6210\u5206\u7684\u70ed\u7194\u80f6<\/p>\n

\u4f5c\u4e3a\u70ed\u7194\u80f6\u4e3b\u6210\u5206\u7684\u805a\u70ef\u70c3\u4e3b\u8981\u662f\u6307\u65e0\u89c4\u805a\u4e19\u70ef\uff08aPP\uff09\u4e0e\u4e19\u70ef\u3001\u4e59\u70ef\u6216\u03b1\u70ef\u70c3\u7684\u5171\u805a\u4f53\u3002aPP\u662f\u751f\u4ea7\u7b49\u89c4\u805a\u4e19\u70ef\u4e2d\u7684\u526f\u4ea7\u7269\uff0c\u7ecf\u7528\u6eb6\u5242\u5206\u79bb\u540e\u53d6\u5f97\u3002\u5b83\u7684\u5206\u5b50\u91cf\u53ca\u7ec4\u6210\u7684\u4e0d\u540c\u4f1a\u4f7f\u70ed\u7194\u80f6\u7684\u7194\u878d\u7c98\u5ea6\u6216\u8f6f\u5316\u70b9\u6e29\u5ea6\u53d1\u751f\u8f83\u5927\u5e45\u5ea6\u7684\u53d8\u5316\u3002\u76ee\u524d\u5e94\u7528\u4e2d\u5e38\u5e38\u8981\u6dfb\u52a0\u4e00\u4e9b\u5176\u4ed6\u6210\u5206\u6765\u964d\u4f4e\u6210\u672c\u6216\u7c98\u5ea6\uff0c\u63d0\u9ad8\u5176\u8010\u70ed\u6027\u548c\u6d41\u52a8\u6027\u3002\u53e6\u4e00\u79cd\u805a\u70ef\u70c3\u4e3b\u6210\u5206\u662f\u6307\u4e19\u70ef\u4e0e\u4e59\u70ef\u6216\u4e0e\u4e01\u70ef\uff0d1\u7684\u5171\u805a\u4f53,\u662f\u975e\u7ed3\u6676\u6027\u6216\u4f4e\u7ed3\u6676\u6027\u7684\u805a\u70ef\u70c3\u6811\u8102\u3002\u5982\u65e5\u672c\u5b87\u90e8V\u30ad\u30bb\u30f3\u516c\u53f8\u5f00\u53d1\u7684\u724c\u53f7\u4e3aAPAO\u7684\u805a\u70ef\u70c3\u6811\u8102\uff0c\u6570\u5747\u5206\u5b50\u91cf\u4e3a3000\uff5e8000\uff0c\u91cd\u5747\u5206\u5b50\u91cf20000\uff5e50000\u3002APAO\u518d\u52a0\u5165\u6709\u5173\u7684\u6dfb\u52a0\u5242\u5236\u5f97\u7684\u70ed\u7194\u80f6\u53ef\u5bf9\u7eb8\u3001\u6728\u6750\u3001\u91d1\u5c5e\u6216PE\u3001PP\u5851\u6599\u8fdb\u884c\u7c98\u63a5\uff0c\u8010\u5bd2\u6027\u53ca\u7c98\u63a5\u64cd\u4f5c\u6027\u5747\u8f83\u597d\u3002\u5176\u4e3b\u8981\u7279\u5f81\u662f\u6210\u672c\u4fbf\u5b9c\u3001\u7c98\u5ea6\u4f4e\u3001\u8f6f\u5316\u70b9\u9ad8\u7b49\u3002<\/p>\n

2.6\u53cd\u5e94\u6027\u70ed\u7194\u80f6\u7c98\u5408\u5242<\/strong><\/p>\n

\u4f5c\u4e3a\u53cd\u5e94\u6027\u70ed\u7194\u80f6\u7c98\u5408\u5242\u7684\u4e3b\u6210\u5206\uff0c\u76ee\u524d\u5df2\u4e0a\u5e02\u9500\u552e\u7684\u6709\u4ee5\u4e0b\u4e24\u79cd\uff1a\u5229\u7528\u7845\u70f7\u9187\uff08Silanol\uff09<\/strong><\/p>\n

\u57fa\u7684\u53cd\u5e94\u548c\u5229\u7528\u6c28\u57fa\u7532\u9178\u916f\u7684\u9884\u805a\u7269\u672b\u7aef\u7684\u5f02\u6c30\u9178\u916f\u57fa\u7684\u53cd\u5e94\u6765\u5b8c\u6210\u4ea4\u8054\u53cd\u5e94\uff0c\u5f62\u6210\u4e09\u7ef4\u7ed3\u6784\uff0c\u4f7f\u5206\u5b50\u94fe\u7684\u7ea6\u675f\u529b\u589e\u52a0\u3002\u5b83\u4eec\u6bd4\u4e0a\u8ff0\u4efb\u4f55\u4e00\u79cd\u70ed\u7194\u80f6\u66f4\u8010\u70ed\u4e0e\u66f4\u8010\u6eb6\u5242\uff0c\u6297\u8815\u53d8\u6027\u80fd\u4e5f\u66f4\u597d\u3002\u8fd9\u7c7b\u53cd\u5e94\u6027\u70ed\u7194\u80f6\u7684\u4e3b\u6210\u5206\u7684\u4ea4\u8054\u53cd\u5e94\u4e3b\u8981\u662f\u4f9d\u9760\u7a7a\u6c14\u4e2d\u7684\u542b\u6e7f\u91cf\u6765\u8fdb\u884c\u7684\uff0c\u6545\u4e5f\u79f0\u4f5c\u201c\u6e7f\u56fa\u5316\u201d\u7684\u70ed\u7194\u80f6\u3002\u5b83\u662f\u8fd1\u5341\u591a\u5e74\u624d\u5f00\u53d1\u51fa\u6765\u7684\u3002<\/strong><\/p>\n

2.6.1\u5229\u7528\u70f7\u6c27\u57fa\u7532\u7845\u70f7\u57fa\u7684\u53cd\u5e94\u6027<\/strong><\/p>\n

EVA\u6216\u5408\u6210\u6a61\u80f6\uff08\u5982SEBS\u7b49\uff09\u7528\u63a5\u679d\u805a\u5408\u5f15\u5165\u70f7\u6c27\u57fa\u7845\u57fa\u4f5c\u4e3a\u53cd\u5e94\u6027\u70ed\u7194\u80f6\u7684\u4e3b\u6210\u5206\uff0c\u7528\u77f3\u6cb9\u6811\u8102\u4e3a\u8c03\u8282\u5176\u7c98\u63a5\u6027\u7684\u6dfb\u52a0\u5242\u3002<\/strong><\/p>\n

\u5229\u7528\u70f7\u6c27\u57fa\u7532\u7845\u70f7\u57fa\u7684\u4ea4\u8054\u53cd\u5e94\u5206\u4e3a\u7845\u70f7\u9187\u53cd\u5e94\u4e0e\u8131\u6c34\u7f29\u805a\u4e24\u6b65\u3002\u53cd\u5e94\u5f0f\u5982\u4e0b\uff1a<\/strong><\/p>\n

\u2460\u7845\u70f7\u9187\u57fa\u53cd\u5e94<\/strong><\/p>\n

R\uff5eSi\uff08OCH3\uff093\uff0b3H2O\u2192R\uff5eSi\uff08OH\uff093\uff0b3CH3OH<\/strong><\/p>\n

\u2461\u8131\u6c34\u7f29\u805a<\/strong><\/p>\n

R1\uff5eSi\uff08OH\uff093\uff0bR2\uff5eSi\uff08OH\uff093\u2192R1\uff5eSi\uff5eO\uff5eSi\uff5eR2\uff0bH2O<\/strong><\/p>\n

\u7ecf\u7528\u7845\u70f7\u63a5\u679d\u7684EVA\u542b\u91cf\u572836\uff05\uff5e42\uff05\uff08m\/m\uff09\u7684\u70ed\u7194\u80f6\u7684\u7c98\u63a5\u6027\u80fd\u5982\u4e0b\u8868\u6240\u793a\u3002<\/strong><\/p>\n

\u7531\u8868\u53ef\u89c1\uff0c\u56fa\u5316\u4ea4\u8054\u540e\u6750\u6599\u7684\u70ed\u5265\u79bb\u5f3a\u5ea6\u6709\u5341\u5206\u660e\u663e\u7684\u63d0\u9ad8\uff08\u7ea6\u63d0\u9ad87\uff5e14\u500d\uff09\u3002<\/strong><\/p>\n

2.6.2\u5229\u7528\u5f02\u6c30\u9178\u916f\u57fa\u7684\u53cd\u5e94\u6027<\/strong><\/p>\n

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